Main Product
Butadienes
Segment
Chemicals
Main-Family
Unsaturated Monomers
Sub-Family
Aliphatic Olefins
Physical State

Gas

Sub-Product
1,2-Butadiene
Alt. Names
Methyl allene; Buta-1,2-diene
Description

1,2-Butadiene is an organic compound with the molecular formula C₄H₆, and it is one of the isomers of butadiene. It is a cumulated diene, meaning it has two adjacent double bonds, making it part of the allene family. Its structure is CH₂=C=CH−CH₃, and it is also known as methylallene.

It is a colorless, flammable gas at room temperature and atmospheric pressure that can be easily liquefied under pressure and it has a characteristic odor.

1,2-Butadiene is a minor byproduct in the cracking of hydrocarbons to produce other C4 compounds like 1,3-butadiene and butenes. It typically constitutes less than 1% of the C4 fraction obtained during this process and can be partially purified through extraction methods such as using N-methylpyrrolidone.

Although it has limited industrial applications compared to 1,3-butadiene, 1,2-butadiene is used in:

  • Specialty gas mixtures.
  • Organic synthesis for research purposes.
  • Instrument calibration.

The toxicity of 1,2-butadiene has not been thoroughly investigated, but it likely acts as a simple asphyxiant and may have anesthetic properties. Due to its flammability and potential health risks, it must be handled with care under controlled conditions. Stabilizers like tert-butylcatechol (TBC) are often added to prevent unwanted reactions during storage or transport. This compound's unique cumulated diene structure makes it chemically distinct from other butadiene isomers, though its lack of extensive industrial use limits its broader significance.

 

A.I. generated description.

Identifiers

logo CAS Number
590-19-2
logo EC Number
209-674-2
logo ECHA InfoCard
100.008.79
logo IUPAC Name
Buta-1,2-diene
logo PubChem ID
11535
Chemical Data

Chemical Formula

C4H6

Molecular Weight (g/mol)
54.092
Boiling Point (°C)
10.9
Melting Point (°C)
-136.2
Sulfur Content (wt%)
0
Specific Gravity
1.87
Properties

Default
Status
A
System Info

Update by
UserPic  Kokel, Nicolas
Updated
2/8/2025 3:16 PM
Added by
UserPic  Kokel, Nicolas
Added
2/8/2025 3:09 PM
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Different molecular representations of 1,2-butadiene https://en.wikipedia.org/wiki/1,2-Butadiene
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Title Date
UserPic 1,2-butadiene added. 2/8/2025