ppPLUS: Technologies and more


Go to Homepage to browse companies and process data

ppPLUS-Solutions providing Services and Support

Register creating your own models

Name
SABIC CTR LDPE
Owner
/ SABIC
Brand
CTR LDPE technology
Process
Polyethylene processes
Type
High-Pressure Polymerization of Ethylene
Available

Technology Summary

The Clean Tubular Reactor Technology (CTR®) is a non-pulsing technology where ethylene is polymerized through a radical reaction initiated by peroxides at a pressure of approximately 2500 bar in a tubular reactor. The reactor is a plug flow type reactor. Not all the ethylene is converted into polymer on the first pass. The unconverted monomer is recycled to the compression section and the produced LDPE, as a melt, is extruded[1].

Technology ownership

The Tubular Reactor Polymerisation of Ethylene technology was originally patented by STAMICARBON N.V. in Fe. 1967[2]. DSM started licensing CTR LDPE in 1995[3]. SABIC inherited the CTR LDPE Technology when it acquired DSM's petrochemicals business in 2022[4].  Today, Technip Energies is the exclusive licensing support contractor of SABIC for the Clean Tubular Reactor LDPE technology[1].

Features of the CTR® LDPE Technology

Claimed advantages of the CTR LDPE Technology are simplicity of design and operation resulting coupled with the so-called 'Clean Tubular Reactor' concept, resultiing in low investment cost, high on-stream times, high prime grade percentage and low manufacturing costs[1,2]

A conceptual Block Flow Diagram (Fig. 1) shows the low pressure cycle, the high pressure cycle, inputs and outputs of the process. The chain transfer agent is added to the booster compressor, ethylene in fed to the primary compressor and recycle is added between primary and secondary compressor stages. In particular, the initiator from cans is blended in minaral oil and the mix is injected via four initiator dosing systems at different points along the reactor lenght (Fig. 2)[2]

Figure 1 - Conceptual Block Flow Diagram of the CTR LDPE Technology[2].

  The characteristics of the CTR LDPE Technology are as it follows[2]

  • Plug flow
  • Design pressure: 3,000 bar
  • Design temperature: 300°C
  • Four reaction peaks
  • Initiators: peroxide only
  • Conversion: up to 38.5%
  • No fouling
  • No pressure pulsing required

Figure 2 - Initiators Injection Points along the CTR Tubular Reactor[2].

The CTR Reactor is claimed to be "Simple" in Design—by comparison with the "Complex" Design of competitor's reactors—resulting in a non-pulsating reactor as depicted in Fig. 3[2].

CTR reactor

  • Uniform tube bore
  • no direct cooling
  • non bumping 
  • low peak temperature
  • high cooling water temperature
  • high initial temperature
  • Pressure: ±​​​ 2,800 bar 

Competitor's reactors

  • Telescope reactor
  • direct cooling
  • bumping
  • /
  • low cooling water temperature
  • low initial temperature
  • Pressure: ≥ 3,000 bar

Figure 3 - Operating Temperature Profiles of the CTR Tubular Reactor[2].

Plant References

More than 10 plants are in operation and Eight references were designed by Technip Energies[1].

Literature

  1. Technip Energies, Oct 2023, Technip Energies Technology Handbook.
  2. STAMICARBON N.V. (NL), GB1196183 (A), Priority date 9th Feb 1967, Process for Preparing Ethylene Polymers or Copolymers.
  3. SABIC, May 2012, SABTEC CTR LDPE Technology, Global Petrochemicals conferennce, Cologne, German. 
  4. Oil&Gas Journal, 3rd Apr 2002, SABIC to acquire DSM's petrochemicals business for almost $2 billion.
Link
System Info

Updated by
UserPic  Kokel, Nicolas
Updated
8/8/2024 6:32 AM
Added by
UserPic  Kokel, Nicolas
Added
7/6/2024 9:01 AM
Solutions
Solutions

Solution-Reference:

#T254

No Services yet available.
Enquire in Solutions how we can help you.

CTR LDPE Technology Simplified Process Flow diagram https://www.ten.com/sites/energies/files/2024-03/Technip_Energies_Technology_Handbook.pdf
CTR LDPE Technology Simplified Process Flow diagram https://www.ten.com/sites/energies/files/2024-03/Technip_Energies_Technology_Handbook.pdf
Entity Site (Country) Asset (Plant)
ASPC ASPC Assaluyeh LDPE Plant
Marun Marun PetChem LDPE Plant
Petkim PETKIM Aliağa LDPE-T
Petlin Petlin Terengganu LDPE Plant
SABIC Europe HQ Sabic Geleen LDPE Plants
Sinopec Qilu Company Qilu Complex LDPE Plant