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🔍 Comprehensive Process Technology Assessment Now Available
Looking for detailed technical intelligence on MDI manufacturing? ppPLUS delivers an in-depth analysis of Mitsui's MDA phosgenation technology that you won't find elsewhere.

📋 What This Analysis Provides:
✅ Patent-based technical specifications from key Mitsui patents
✅ Quantified operating parameters
✅ Detailed reactor configurations with multistage stirred tank designs
✅ Process integration analysis
✅ Performance benchmarks
✅ Equipment specifications

#processtechnology #chemicalengineering #mdi #isocyanate #phosgenation #basf #dow #huntsman #covestro #sumitomo #wanhua #busschemtech #mitsui



The ODC principle is based on the reduction of oxygen at the cathode. The oxygen then reacts with the hydrogen ions, which migrate through the membrane from the anode side of the cell. This suppresses the generation of hydrogen and forms water (H2O):

Chemical equations:

  • Anode (oxidation):
  • Cathode (ODC reduction):
  • Overall:

2 Cl⁻ → Cl₂ + 2e⁻
O₂ + 4 H⁺ + 4e⁻ → 2 H₂O
4 HCl + O2 → 2 Cl2 + H2O

Compared to the Standard reaction for hydrogen generation, the ODC Process reduces the required operating voltage by approximately 1 volt, resulting in consequent energy savings.

The ODC process find applications in isocyanate plants by recycling HCl from phosgene production, for chlorine recovery from various HCl waste streams, and in integrated chemical complexes where hydrogen is not required.

#electrolyzer #electrolysis #hydrogenchloride #hclrecycling #odc #isocyanate #chlorinerecovery #thyssenkrupp #covestro #denora #phosgene




Just published a comprehensive update on HCl electrolysis technology in the Portfolio Planning PLUS Ltd database - a critical process for chlorine recovery, in particular in isocyanate manufacturing.

KEY HIGHLIGHTS:
✅ Three commercial technologies compared: ODC, Diaphragm, and Membrane cells
✅ Energy efficiency gains: ODC process delivers 30% energy savings (733-1070 kWh/t Cl₂)
✅ Process integration: Detailed plant configurations for each technology variant
✅ Industrial applications: Focus on chlorine recycle in MDI/TDI production

#chemicalengineering #processtechnology #isocyanates #chlorinerecovery #hclrecycling #denora #thyssekruppnucera #covestro



🚀 We just published a comprehensive new technology resource on ppPLUS covering Amine Phosgenation to Isocyanate processes - the dominant commercial route for producing essential polyurethane raw materials including TDI, MDI, HDI, and specialty isocyanates.

🔎 What's Covered:
✓ Historical development from IG Farben's 1936 breakthrough to today's advanced processes
✓ Detailed process descriptions for both liquid-phase and gas-phase technologies
✓ Practical operating conditions based on patent examples and commercial data
✓ Technology limitations and applicability ranges for different amine feedstocks
✓ Comprehensive industry overview covering major producers and technology providers
✓ Process economics and efficiency comparisons between different approaches

🏭 Industry Relevance:
This resource provides technical professionals with essential insights into the $50+ billion global isocyanate industry, covering technologies from market leaders including Wanhua Chemical, BASF, Covestro, Huntsman, Dow, and Mitsui Chemicals.

💡 Key insights include:
◾ Why liquid-phase processes dominate (universal applicability)
◾ Where gas-phase technology offers advantages (energy savings for volatile amines)
◾ Practical temperature/pressure ranges for commercial operations
◾ Technology licensing landscape and market concentration

#chemicalengineering #processtechnology #isocyanates #polyurethanes #phosgenation #wanhua #covestro #basf #huntsman #dow #mitsui #khumo #kmci #chloralkali





The Mitsui carbonyl chloride (phosgene) technology is a process that is integrated with the isocyanate manufacturing process.

We have analyzed Mitsui patents to reverse engineer the process and generate a simplified process flow diagram.

#mitsui #phosgene #carbonylchloride #isocyanate #chlorine #carbonylation




Methylene Diphenyl Diisocyanate (MDI) is a reactive chemical intermediate with the molecular formula C₁₅H₁₀N₂O₂ and molecular weight of 250.25 g/mol. It serves as an essential building block in the production of polyurethanes, urethane-prepolymers, and polyisocyanurate polymers across diverse industries.
#mdi #pmdi #isocyanate #polyurethane